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Influence of Overprotection on AC Corrosion. Analysis of a Real Case
Ivano Magnifico, Certified Senior Technician in Cathodic Protection.
Meet the Author
Ivano Magnifico holds a master’s degree in Electronic Engineering and serves as the Gas and Oil Product Manager at Automa, an ICorr Corporate Member.
A certified Cathodic Protection Specialist, he combines technical competence with deep knowledge of market analysis and industry standards. With over 15 years of experience in remote cathodic protection monitoring and a patent for an intelligent reference electrode, Ivano has made significant contributions to the field. He is a member of the Board of Directors of CEOCOR (European Committee for the Study of Corrosion and Protection of Piping Systems) and serves as the Delegate of the AMPP Italy Ivano Magnifico Chapter. In addition, he is an active participant in ISO and AMPP standard working groups on cathodic protection.
Introduction
The risk of AC corrosion has always been linked to the parallelisms of underground pipelines with High Voltage AC lines, especially in those geographical areas where the morphology of the territory creates obligatory so-called “technological corridors” and therefore forces the coexistence of different services over long distances.
Recently, the greater diffusion of AC-powered railway networks has further increased the AC interfering sources, while the use of more performing coatings on underground pipelines has on the one hand increased their insulation from the surrounding soil, and on the other has increased the risk of overprotection compared to old, less performing, or more degraded coatings.
This paper, starting from a real case found in a gas distribution network, will present the normative criteria to be used to keep
the AC corrosion risk under control, and will highlight how the simultaneous presence of cathodic overprotection may result in an autocatalytic cycle leading to accelerated AC corrosion, in which monitoring becomes essential in order to be able to carry out on time the appropriate corrective actions.
There are several mechanisms through which an AC source can interfere with a metal structure (Fig. 1): by inductive coupling,
as an effect of the magnetic field generated with respect to an underground structure; by capacitive coupling, in the case of an aerial structure; and by conductive coupling in the presence of a fault current in the ground, in the case of an underground pipeline.
In the case of underground pipelines, under normal operating conditions, the mechanism that can generate AC interference is inductive coupling: normally the interference effect is greater as larger the length of the sections where the pipeline and the AC source (high voltage AC lines, railways operated in AC) follow a parallel path.
AC Corrosion Protection Criteria
International industry standards specify which electrical parameters shall be monitored and their maximum allowed values. The standard ISO 18086:2019 “Corrosion of metals and alloys – Determination of AC corrosion – Protection criteria” indicates two steps for the verification of permissible AC interference levels (Fig.2):
The first step relates to a safety criterion for maximum permissible touch voltage (15V threshold) and does not have a direct rule in AC corrosion risk assessment. This value considers a hand-to-hand or hand-to-foot resistance for an adult male human body of 1500 Ω, yielding a current flow of 10 mA when 15 V is applied [2].
The criterion is based on current density measurements carried out through a coupon whose surface is defined by the standard to be 1 cm², connected to the structure. Both AC current density and DC current density must be measured, as the level of cathodic protection can affect the AC corrosion phenomenon.
NACE standard SP21424-2018 “Alternating Current Corrosion on Cathodically Protected Pipelines: Risk Assessment, Mitigation, and Monitoring” [3] expresses similar values, where depending on the measured DC current density (J.dc) value, different levels of AC current density (J.ac) are allowed:
• If J.dc > 1 A/m2 then J.ac < 30 A/m2; or
• If J.dc < 1 A/m2 then J.ac < 100 A/m2
This standard imposes a maximum AC current density limit even if the DC current density is less than 1 A/m², while the coupon surface of 1 cm² is indicated as generally used but not mandatory.
The Spread Resistance is the ohmic resistance through a coating defect towards remote earth and controls the DC (Idc) or AC (Iac) current passing through a defect at a given voltage (Udc or Uac):
Uac = R’s Iac or Uac = Rs J.ac (1)
where Rs is the normalized Spread Resistance expressed in Ω·m2.
On coating defects, where cathodic protection current reaches the steel surface, cathodic reactions occur involving oxygen reduction and hydrogen evolution. Both reactions generate hydroxide ions(OH-) leading to increased pH at the interface and alkalinity.
Since Spread Resistance depends [4] on both defect size (decreases as surface decreases) and pH value at the interface (decreases as pH increases), the DC current density reaching the defect affects it:
Lower current density leads to decreased pH value and increased Spread Resistance.
Higher current density leads to increased pH value and decreased Spread Resistance.
This is where overprotection can have an effect on AC corrosion:
Presence of a very electronegative IR-free potential (due to high DC current densities);
• Decrease in the Spread Resistance value;
• Possibility of significant AC current density even with low measured AC voltage.
Regarding the choice about which size of coupon to use, increasing the surface area of the coupon results in a lower average current density since the spread resistance increases linearly with increasing defect diameter and the current density decreases linearly with surface area.
Therefore, the current density is typically underestimated when the surface area of the coupon is chosen to be larger than the maximum defect size on the structure: for this reason, in the case of AC corrosion, the standards indicate the use of a 1 cm2 coupon.
AC Corrosion Mechanism in the Presence of Over-Protection [3]
For pipelines with applied cathodic protection, AC corrosion development requires simultaneous coexistence of induced AC, excessive cathodic protection, and small coating defects. Under these conditions:
1. Induced alternating current leads to alternating current discharge on coating defects.
2. AC current density is regulated by alternating voltage and spread resistance associated with the coating defect, through Ohm’s law.
3. Spread resistance depends on:
a. Coating defect size.
b. Soil resistivity near the defect.
c. Soil chemistry.
d. Cathodic protection current density in the coating defect.
Figure 3 – Autocatalytic Nature of AC Corrosion on Cathodically Protected Pipelines Described by Sp21424.
As shown in Fig.3, the AC current density can lead to the depolarisation of the defect: this requires a higher DC current density to maintain a certain cathodic protection potential. Increasing the level of cathodic protection to mitigate AC corrosion, in this case, has the opposite effect: the increase in DC current density further decreases the Spread Resistance at the coating defect due to the production of OH- ions (alkalinisation). Through high levels of cathodic protection, the Spread Resistance decreases, thus increasing the density of alternating current, restarting the cycle: this scenario results in an autocatalytic cycle leading to AC corrosion.
It therefore becomes clear that, in order to leave this cycle, it is necessary to control both the AC current density and the DC current density.
Analysis of A Real Field Case
The case that will be shown has been detected on a measurement point of the distribution network of a large European city, with the following features:
• An extensive cathodic protection system forming a ring around the city center with radiating offshoots.
• Multiple crossings with DC powered railways and surface metro.
• Multiple parallels with the HVAC network.
• Cathodic Protection guaranteed by two T/Rs.
The analysed measuring point (MP):
• Located in a CP system area with several km of parallelism with HVAC line.
• Local soil resistivity between 25 and 50 Ω·m.
• Equipped with permanent CSE reference electrode with integrated 10 cm² coupon (measured current density is underestimated compared to 1 cm² coupon).
• Equipped with a G4C-PRO remote monitoring device capable of performing instant-off measurements on coupon and current density measures.
The measurements shown in Table 1 correspond to daily reports calculated on measurements performed continuously at a frequency of 1 Hz (1 measure per second) for each measuring channel. The minimum, average and maximum daily values are shown over a period of 4 days:
• Eon.dc: ON potential (DC) expressed in V CSE;
• Eon.ac: ON potential (AC) expressed in V;
• E off: instant-off on coupon, equivalent to IR-Free potential
(measured, every second, after a 1 ms wait from switch opening and over a 20 ms interval) expressed in V CSE;
• mIon: DC polarisation current of the coupon expressed in mA; as the coupon size is 10 cm2 the shown value corresponds to the current density in A/m2;
• mIon.ac: AC polarisation current of the coupon expressed in mA; as the coupon size is 10 cm2 the shown value corresponds to the current density in A/m2 (note: the current density value measured on a 1 cm2 coupon would be significantly greater than that measured on the 10 cm2 coupon).
In the absence of coupons, the only available measures would be Eon.dc and Eon.ac, and, on these values, the only possible evaluation would be that relating to the first step of ISO 18086, which would be absolutely respected considering that the highest AC average value along the four days shown (0,424 V) is well below the indicated threshold of 15V. Generally, such a low AC voltage value would never suspect a real risk of AC corrosion, but as can be detected from the DC and AC current densities, we are faced with unacceptable interference levels:
• mIon: between 15 A/m2 and 17 A/m2:
o greater than the threshold of 1 A/m2 for which (according to ISO 18086) the AC current density value would be indifferent.
• mIon.ac: between 35 A/m2 and 39 A/m2:
o greater than the threshold of 30 A/m2 indicated by ISO 18086 and NACE SP21424.
The explanation for this situation is given precisely by the significant level of cathodic overprotection present, represented by IR-Free potential values more negative than -1.3 V CSE and very high DC current density values, being the MP in a site suffering cathodic DC interference generated by metro and railway systems.
This results in a reduction of the Spread Resistance value, up to the point of generating an AC current density higher than the allowed limits even in the presence of a very low AC voltage.
The main evidence of the dependence of this condition on over-protection has been clearly shown when, due to a malfunction, one of the two T/Rs protecting the Cathodic Protection system did shut down, changing the values measured on the Measurement Point as in Table 2:























