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Tuesday 22nd August 2023 – Annual-fund-raising Corrosion Awareness Day (CAD)

Aberdeen Branch

On Tuesday 22nd August 2023 the Aberdeen Branch held its annual fund-raising Corrosion awareness Day (CAD) and welcomed eight corrosion industry speakers along with multiple equipment demonstrations from Rysco, who were ICorr’s host for this one special event. CAD is designed to assist the development of those unfamiliar with Corrosion & it’s prevention and provides and understanding of the corrosion processes and causes which are specific to a range of common industries.

Delegates learnt the basics of the role of the corrosion engineer; including materials selections, corrosion mitigations; failure investigation; testing and design issues.

Delegates – Group Photo

The Welcome was provided by the Aberdeen Branch Chair, Siji Anjorin supported by Dean Smith, Bridge of Don Operations Manager for Rysco U.K for the Safety Moment.

Rysco are headquartered in Calgary and are a global provider of Corrosion Management Solutions. They are both an ICorr Gold Sustaining Member and Aberdeen Local Branch Sponsor.

Compiled: Nigel Owen and Stephen Tate

Dean Smith, Operations Manager for Rysco U.K

A comprehensive series of Talks and Demonstrations followed the Introductions, designed to cover all they key Corrosion Topics.

1. Principles and Costs of Corrosion

Steve Paterson, Ph.D, C.Eng, Arbeadie Consultants provided the opening presentation running through the fundamentals of corrosion and electrochemistry with emphasis on what drives corrosion and the corrosion process of metals. He then outlined the different types of corrosion and common corrosion mechanisms and how these related to the Oil & Gas industry. Internal Corrosion mechanisms discussed were: Acid gas corrosion (CO2/H2S) consisting: CO2 (sweet) corrosion, Preferential weld corrosion, H2S (sour corrosion, Mixed sweet & sour corrosion), Sulphide stress cracking (SSC), Hydrogen induced corrosion (HIC), Hydrogen embrittlement, Chloride pitting/crevice corrosion, Oxygen corrosion, Microbial induced corrosion (MIC) and Sand erosion.

Several methods of corrosion control and management were outlined including:

• Materials selection: The most effective solution that can remove the corrosion threat completely (e.g. CRA/Non-metallic material).
• Water removal by dehydration.
• Chemical treatments (e.g. corrosion inhibitor, biocide or oxygen scavenger) a common mitigation method for internal protection of carbon steels.
• Use of Coatings and linings.
• Anodic/Cathodic protection used to limit and control Corrosion in both internal and external situations.
• Control of process parameters/environment, e.g. by limiting temperature and chloride content can reduce the risk of SCC.

Steve then highlighted the costs and significance of corrosion and demonstrated how implementing corrosion prevention best practices could result in savings of between 15% and 35% with the NACE 2016 study quoting savings of 3.4% of global GDP (Gross Domestic Product), giving immense motivation for corrosion engineers to contribute in achieving such savings and associated improvements in integrity of infrastructure and protection of the environment

2. Materials Selection

Rob Howard, PhD, of Lloyd’s Register discussed materials selection critical to the Oil & Gas processing industry making reference to a process diagram from well to final product, he looked at the common types of corrosion witnessed in the process equipment: A selection of materials for corrosion resistance was reviewed showing how we can move from Martensitic and Austenitic Stainless steels up to Duplex and onto Ni and Titanium alloys to get sufficient resilience, albeit with some heavy cost implications.

Rob Howard graduated with a in Materials Engineering from the University of Cape Town in 1995. and worked as a post-doctoral researcher at the Corrosion and Protection Centre, University of Manchester. He joined Lloyd’s Register in 1998 and at present he is the team leader for the Offshore Materials team in LR, whose main function is to provide technical support to surveyors and clients and to review design specifications for oil and gas and offshore wind projects.

He explained how the choice of equipment materials is influenced by parameters such as corrosivity, flowrates and chloride and hydrogen sulphide levels. However, equally important are the heat treatment condition and mechanical properties required, the corrosion resistance and issues such as weldability and ongoing costs for inspection maintenance and repair of materials selected. Rob referenced a number of international sources which are particularly useful for materials selection and stressed the need to examine Manufacturer capability and quality control of the product:

• Norsok M-001 (edition 5, Sept 2014)
• ISO 21457
• ISO 15156 (NACE MR-0175)

3. Oilfield Microbiology Analysis and Data Trending

Carol Devine, PhD, BSc (Hons) of NICMB has over twenty-five years’ experience in oilfield microbiology. She has a particular interest in microbiologically influenced corrosion (MIC), sulphate-reducing bacteria (SRB), seawater injection systems and molecular microbial ecology in general. NCIMB preserve, store and supply a collection of cultures to industry and universities with the largest collection of industrial, marine and food bacteria in the UK and have approx. 10,000 strains; 300 genera; 2000 species – and still growing.

Oilfield equipment is commonly damaged by the presence and activity of micro-organisms in systems for Production, Seawater Cooling, Water Injection, Cooling/Heating and in handling of Produced Water, Firewater, reinjection (PWRI), Diesel Storage & Ballast Water. The Organisms are either Planktonic from bulk water phases or Sessile biofilms on surfaces.

Carol explained the role of the oilfield microbiologist in generating useful and appropriate data in order to:

• Predict which particular systems, vessels, pipelines, locations are under threat from microbiologically influenced corrosion (MIC)
• Prioritise areas for treatment according to budget and time available
• Apply and monitor appropriate strategies to mitigate against the effects of MIC or biofouling

Techniques for analysis where explained: Triplicate MPN’s, qPCR and Metagenomic Analysis (NGS) to assess the threat of MIC and to quantify, identify and assess the activity which needs to be monitored on a continuous basis to see trends from production changes and implement actions to control and prevent system infestation which affects flow and efficiency in the process.

4. Corrosion Mitigation by Cathodic Protection

Dr. Nigel Owen, B.Sc., D.I.C, Ph.D., MIMMM, MICorr, Aberdeen Foundries has worked in the Aluminium Industry for over 35 years on alloy development and manufacturing processes, spending his later years at Aberdeen Foundries as Sales, Technical and Plant Manager, manufacturing Sacrificial Anodes He now oversees manufacturing, testing and design of all subsea and marine sacrificial anode systems.

Nigel explained how the Galvanic table shows naturally what materials are suitable as bases for sacrificial anodes. Aluminium, Zinc and Magnesium being the primary common bases for development of the alloys. With a sufficiently electronegative potential the base material can be alloyed with other elements to make it more electronegative and efficient as an anode. Aluminium has a high current output per Kg consumed and therefore has become the material of choice for anodes, particularly on large structures.

His presentation covered:
• Alloys for Sacrificial Anodes
• Design of a CP system to protect a structure
• Applications of Anodes
• The selection of the CP system:
• The pro’s and con’s of Sacrificial and Impressed systems and their applications.

The process of designing of a sacrificial anode system was explained from assessment of (cathode) material areas and the effect of coating to the calculation of anode mass and current output for a structure in an immersed environment.

Comparison was made between Sacrificial and impressed current systems in terms of their benefits or advantages in given current demand situations and maintenance requirements. Performance being determined by the conductivity (salinity) and the temperature (water depth/ geographic region) of deployment.

5. Corrosion Mitigation by Coatings

Colin Thomson HND, FM Lead at Bilfinger Salamis, has over 20years experience working in oil and gas fabric maintenance after serving in the Merchant Navy. He has supported various clients FM requirements including, BP, and Conoco Phillips, ExxonMobil and Petrofac. He skilfully explained how Fabric Maintenance prevents corrosion, degradation and wear which could otherwise lead to safety and or operational issues. Coatings acts as a barrier to the environment therefore all locations where coatings are damaged must be maintained to prevent metal loss. Colin also brought everyone up to date with modern FM strategies and also instantaneous barrier methods such as anti-corrosion tapes (ACTs) and Corrosion Inhibiting Waxes.
Various key properties of coatings were highlighted including:

• Anti-Fouling
• Environmental Protection
• Fire Protection
• Process Flow aids.
• Safety
• Thermal protection / insulation

The complete range of surface preparation techniques were evaluated along with all factors affecting coating ‘Life Expectancy’ for example:

• Anchor Pattern (too rough or too smooth)
• Chemical Salts
• Condensation
• Existing Coatings
• Fabrication Defects (weld spatter, sharp edges)
• Mill Scale
• Oil, grease and soil
• Surface Corrosion

6. Corrosion and Chemicals Management

Jennifer Watson HNC, Senior Account Manager/Production Chemist at Champion X is currently based within the BP office supporting Glen Lyon FPSO and has over 20 years experience in Oil & Gas operations offshore and onshore. She enthusiastically described all the key chemical mitigations deployed within the energy sector including:

• Biocides for preventing MIC
• Corrosion inhibitors for internal corrosion
• Drag reduction
• Oxygen and H2S scavengers pH stabilization

Jen also discussed all commonly used monitoring processes and analysis methods for rates, chemical residuals and other dosing checks. Most importantly she emphasised the need for having appropriate Chemical & Corrosion Control Matrices (CCCM) in place. These are the basis for understanding individual threats and how they should be mitigated by applied chemical application or other barriers.
A magnificent Lunch followed with an opportunity for all to network.

One of many Networking Opportunities.

7. Integrity Management and Risk Based Inspection.

Simon Hurst, BSc, MSc has been with CAN since 2008 and is currently the Engineering Director where he is responsible for the ENGTEQ business stream and is the nominated Technical Manager under their UKAS Accreditation for Integrity Management and Pressure Systems Inspection. He commenced his talk by defining Integrity Management – BS ISO 55000:2014 states that it enables an organization to achieve its objectives through the effective and efficient management of its assets. The application of an asset management system provides assurance that those objectives can be achieved consistently and sustainably over time.

Simon went on to define some of the key components of Asset Integrity Management including the following:

• Ageing and Life Extension
• Anomaly Management
• Corrosion Control Matrices
• Failure Investigations
• Integrity Operating Windows
• Risk Based Assessments leading to Risk Based Inspection

He then defined with good detail the nature of risk and the various different methodologies for Risk Based Assessment. In relation to CRA’s Simon usefully highlighted that:

• Although the use of corrosion resistant alloys generally leads to an increase in the time between inspections, the subsequent inspection of those CRAs is normally significantly more problematic than say on Carbon Steel.
• The use of CRAs (v CS) doesn’t normally lead to a significant increase in the periodicity for the first in-service inspection as this is more about identifying fabrication type defects than in-service damage.
In closing he reminded Delegates that it is best practice to create a “Written Scheme of Examination” (WSE) that details the applicable degradation mechanisms, and the precise location and inspection technique that will be used in order to try and either find the mechanism or confirm its absence.

8. Corrosion and Erosion Monitoring

Dean Smith is an experienced Operations Manager in the Corrosion Monitoring industry, having started his career as a Retrievals Technician in 2007 and worked his way up to field services management and eventually operations management. He emphasised that erosion and corrosion pose significant challenges to oil and gas production, impacting safety, efficiency, and profitability and effective monitoring techniques, combined with ongoing innovation and investment, are essential to mitigate these challenges and ensure the sustainability of the industry.
Prior to the practical demonstrations, Dean gave a run-through of the key services of Rysco UK which cover the following:

Design & Supply of Internal Corrosion Monitoring Systems including: High & Low Pressure Access Systems:

• Custom Equipment Design & Manufacturing
• Electronic Monitoring, e.g., Electrical Resistance Instruments
• Injection & Sampling Systems
• Mechanical Monitoring, e.g., Corrosion Coupons

Field Services including: High and Low Pressure Monitoring Device Retrieval.

• Hot Tapping
• Monitoring Data Analysis and Reporting
• Monitoring System Audits
• Sampling and Lab Analysis

Online Reporting including: Custom Reporting Dashboards via Business intelligence Software and Interactive Mapping

Sponsor’s Process Equipment Demonstrations
Three separate demonstrations followed for which the 52 strong gathering was split into 3 rotating groups.

Richard Rae of Rysco U.K explains Integrated Corrosion Data Management

Retrieval Tool Demonstration

Corrosion Coupon Review

A Corrosion Quiz covering multiple aspects of the Speaker Presentations followed by a vote of thanks from the President and CPD awards closed this very successful event attended by over 50 delegates.

Delegates enjoying the Corrosion Quiz

ICorr Aberdeen welcomes suggestions for further Industrial visits.

Abstracts of potential papers for the Aberdeen Technical Programme are always welcome, and anyone wishing to join committee should correspond with the 2023/2024 Technical Programme Co-ordinator: Adesiji Anjorin anjorin@gmail.com

Further Information about the Aberdeen Branch, and past presentations, may be found on their website page: Aberdeen Branch – Institute of Corrosion (icorr.org), and to join the Aberdeen Branch mailing list, please contact: icorrabz@gmail.com